Name: 
 

O-chem Practice



Multiple Choice
Identify the choice that best completes the statement or answers the question.
 

 1. 

Which of the following diatomic molecules is joined by a double covalent bond?
a.
mc001-1.jpg
c.
mc001-3.jpg
b.
mc001-2.jpg
d.
mc001-4.jpg
 

 2. 

What type of hybridization occurs in the orbitals of a carbon atom participating in a triple bond with another carbon atom?
a.
mc002-1.jpg
c.
mc002-3.jpg
b.
mc002-2.jpg
d.
mc002-4.jpg
 

 3. 

What is thought to cause the dispersion forces?
a.
attraction between ions
c.
sharing of electron pairs
b.
motion of electrons
d.
differences in electronegativity
 

 4. 

Which of the forces of molecular attraction is the weakest?
a.
dipole interaction
c.
hydrogen bond
b.
dispersion
d.
single covalent bond
 

 5. 

Why are the molecules of hydrocarbons nonpolar?
a.
The intermolecular attractions are strong.
b.
All the bonds are single covalent bonds.
c.
The electron pair is shared almost equally in all the bonds.
d.
Van der Waals forces overcome polarity.
 

 6. 

Which of the following compounds is an unsaturated hydrocarbon?
a.
methane
c.
nonane
b.
propyne
d.
methyl
 

 7. 

A structural isomer of hexane is ____.
a.
2,2-dimethylbutane
c.
benzene
b.
cyclohexane
d.
2-methylpentene
 

 8. 

Which of the following molecules does NOT display resonance?
a.
benzene
c.
m-xylene
b.
phenylethane
d.
cyclohexane
 

 9. 

Which carbon skeleton represents an ester?
a.

CCCCCOCC
c.

mc009-2.jpg
b.

mc009-1.jpg
d.

mc009-3.jpg
 

 10. 

What is the expected product when l-propanol is oxidized?
a.
propanal
c.
propanoic acid
b.
propanone
d.
propene
 

 11. 

Which of the following bonds is the least reactive?
a.
C—C
c.
O—H
b.
H—H
d.
H—Cl
 

 12. 

How is a pair of molecular orbitals formed?
a.
by the splitting of a single atomic orbital
b.
by the reproduction of a single atomic orbital
c.
by the overlap of two atomic orbitals from the same atom
d.
by the overlap of two atomic orbitals from different atoms
 

 13. 

What causes water molecules to have a bent shape, according to VSEPR theory?
a.
repulsive forces between unshared pairs of electrons
b.
interaction between the fixed orbitals of the unshared pairs of oxygen
c.
ionic attraction and repulsion
d.
the unusual location of the free electrons
 

 14. 

Experimental evidence suggests that the H—C—H bond angles in ethene, Cmc014-1.jpgHmc014-2.jpg, are ____.
a.
90mc014-3.jpg
c.
120mc014-5.jpg
b.
109.5mc014-4.jpg
d.
180mc014-6.jpg
 

 15. 

What causes dipole interactions?
a.
sharing of electron pairs
b.
attraction between polar molecules
c.
bonding of a covalently bonded hydrogen to an unshared electron pair
d.
attraction between ions
 

 16. 

Which type of solid has the highest melting point?
a.
ionic solid
c.
metal
b.
network solid
d.
nonmetallic solid
 

 17. 

How many carbons are in a molecule of hexane?
a.
3
c.
5
b.
4
d.
6
 

 18. 

What is the physical state of the smallest alkanes at room temperature?
a.
gas
c.
solid
b.
liquid
d.
gas or liquid
 

 19. 

In which of the following compounds does rotation occur around all covalent bonds between carbons?
a.
octene
c.
octane
b.
octyne
d.
all of the above
 

 20. 

Which of the following compounds is a structural isomer of butane?
a.
2-methylbutane
c.
2-methylpropane
b.
2,2-dimethylbutane
d.
2,2-diethylpropane
 

 21. 

Which of the following is true about structural isomers?
a.
Structural isomers have the same molecular formula.
b.
Structural isomers have different physical and chemical properties.
c.
Structural isomers have the same elemental composition.
d.
all of the above
 

 22. 

Which of the following is NOT an important fossil fuel?
a.
petroleum
c.
natural gas
b.
hydrogen
d.
coal
 

 23. 

What is the carbon skeleton of the product formed in the following reaction?
Cmc023-1.jpgHmc023-2.jpg + HBr
a.

mc023-3.jpg
c.

mc023-4.jpg
b.

CCCBr
d.

CCBrC
 

 24. 

Which of the following alcohols is used in antifreeze?
a.
ethanol
c.
ethylene glycol
b.
isopropyl alcohol
d.
glycerol
 

Short Answer
 

 25. 

Write the general structure for ester compounds.
 

 26. 

Write the general structure for carboxylic acid compounds.
 

Essay
 

 27. 

What are dispersion forces? How is the strength of dispersion forces related to the number of electrons in a molecule? Give an example of molecules that are attracted to each other by dispersion forces.
 

 28. 

Compare the properties of the alcohols with the properties of the halocarbons and the alkanes.
 



 
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